Journal cover Journal topic
Annales Geophysicae An interactive open-access journal of the European Geosciences Union
Journal topic

Journal metrics

Journal metrics

  • IF value: 1.585 IF 1.585
  • IF 5-year value: 1.698 IF 5-year
    1.698
  • CiteScore value: 1.62 CiteScore
    1.62
  • SNIP value: 0.820 SNIP 0.820
  • IPP value: 1.52 IPP 1.52
  • SJR value: 0.781 SJR 0.781
  • Scimago H <br class='hide-on-tablet hide-on-mobile'>index value: 83 Scimago H
    index 83
  • h5-index value: 24 h5-index 24
Volume 23, issue 3
Ann. Geophys., 23, 781-797, 2005
https://doi.org/10.5194/angeo-23-781-2005
© Author(s) 2005. This work is distributed under
the Creative Commons Attribution 3.0 License.
Ann. Geophys., 23, 781-797, 2005
https://doi.org/10.5194/angeo-23-781-2005
© Author(s) 2005. This work is distributed under
the Creative Commons Attribution 3.0 License.

  30 Mar 2005

30 Mar 2005

Prediction and modelling of doubly-charged ions in the Earth's upper atmosphere

C. Simon1, J. Lilensten1, O. Dutuit2, R. Thissen2, O. Witasse3, C. Alcaraz4, and H. Soldi-Lose2 C. Simon et al.
  • 1Laboratoire de Planétologie de Grenoble, Grenoble, France
  • 2Laboratoire de Chimie-Physique, Centre Universitaire, Orsay, France
  • 3Research and Scientific Support Department of ESA, ESTEC, Noordwijk, The Netherlands
  • 4Laboratoire LURE, Centre Universitaire Paris-Sud, Orsay, France

Abstract.

We discuss the existence of the doubly-charged ions N2++, O2++ and O++ in the Earth's ionosphere through the theoretical computation of density profiles over the altitude range 100-500km calculated with the TRANSCAR model. Photoproductions and electron impact productions are described in detail. The photochemical equilibrium assumption verified in this context yields density profiles, validated by comparison to the measurements of the satellite Atmosphere Explorer. Those three dications are lost essentially by dissociative recombination and collisions with the neutrals N2, O2 and O. The metastable lifetime of N2++ is 3s and is estimated at 4s for O2++. A survey of the sensitivity to geophysical parameters (solar activity, latitude and solar zenith angle) is also shown. Emphasis is cast on the need for rate constants for chemical reactions involving doubly-charged ions. The fit of the model yields an estimated value of 1.06±0.40x10-10cm3s-1 for the rate constant of the O+++O reaction.

Publications Copernicus
Download
Citation
Share