| Volumes and Issues Contents of Issue 5 Special Issue |
www.ann-geophys.net/26/1149/2008/
doi:10.5194/angeo-26-1149-2008
© European Geosciences Union 2008
The study of intermolecular energy transfers in electronic energy quenching for molecular collisions N2-N2, N2-O2, O2-O2
Polar Geophysical Institute of the Kola Science Centre RAS, Apatity, 184209, Russia
Abstract. Contributions of intermolecular electron energy transfers in the electronic quenching are calculated for molecular collisions N2(A3Σu+, W3Δu)+N2(X1Σg+, v=0), N2(A3Σu+)+N2(X1Σg+, v≥0), N2(A3Σu+)+O2(X3Σg−, v=0–2), O2(a1Δg, b1Σg+)+O2(X3Σg−, v=0–2). The calculation has allowed one to estimate the product branching ratios. It is shown that there is a dependence of the calculated rate coefficients on the vibrational excitation of N2(X1Σg+) and O2(X3Σg−) molecules. In many cases, the calculated rate coefficients have a good agreement with available experimental data.
Full Article (PDF, 1024 KB)
Citation: Kirillov, A. S.: The study of intermolecular energy transfers in electronic energy quenching for molecular collisions N2-N2, N2-O2, O2-O2, Ann. Geophys., 26, 1149-1157, doi:10.5194/angeo-26-1149-2008, 2008. Bibtex EndNote Reference Manager XML
